Preheat oven to 350℉.
In a medium mixing bowl, whisk together the dry ingredients (flour, baking powder, salt, cinnamon, ginger, cloves, nutmeg and black pepper. Set aside.
In a separate medium bowl, whisk together the melted butter, brown sugar, sourdough starter, molasses, eggs, and vanilla until slightly light and fluffy.
Add the flour mixture to the bowl with the wet ingredients and use a rubber spatula or wooden spoon to mix until just fully combined.
Turn the dough onto a liberally floured work surface. Cut the dough into two equal pieces.
With floured hands, shape each half of the dough into rectangles measuring approximately 12 inches long, 3 inches wide, and 1 inch thick. If the dough is too sticky, sprinkle some flour over the surface of the dough.
Transfer both rectangles of dough to a large baking sheet lined with parchment paper, spacing them at least 2 inches apart.
Bake for 25 minutes. Remove the baking sheet from the oven and allow to cool at room temperature for 30 minutes.
Transfer the baked rectangles to a large cutting board and use a large kitchen knife or serrated knife to cut the biscotti into 1 inch wide pieces.
Return the biscotti to the baking sheet cut side up. They can be spaced very close to each other for the final bake.
Bake for an additional 30 minutes, carefully flipping the biscotti halfway through.
Allow to cool completely before drizzling with white chocolate.